Ultrafast Ion Transfer of Metal-Organic Framework Interface for Highly Efficient Energy Storage
Chao Lu1*（陆超）, Xi Chen2
1College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
2Department of Earth and EnvironmentalEngineering, Columbia University, New York, New York10027, United States
Nano Lett. 2024, 24, 10, 3267–3272
Abstract: Flexible supercapacitors are favorable for wearable electronics. However, their high-rate capability and mechanical properties are limited because of unsatisfactory ion transfer kinetics and interfacial modulus mismatch inside devices. Here, we develop a metal–organic framework interface with superior electrical and mechanical properties for supercapacitors. The interfacial mechanism facilitates ultrafast ion transfer with an energy barrier reduction of 43% compared with that of conventional transmembrane transport. It delivers high specific capacity at a wide rate range and exhibits ultrastability beyond 30000 charge–discharge cycles. Furthermore, meliorative modulus mismatch benefited from ultrathin interface design that improves mechanical properties of flexible supercapacitors. It delivers a stable energy supply under various mechanical conditions like bending and twisting status and displays ultrastable mechanical properties with performance retention of 95.5% after 10 000 bending cycles. The research paves the way for interfacial engineering for ultrastable electrochemical devices.
链接：//pubs.acs.org/doi/10.1021/acs.nanolett.4c00408
