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顾宏伟教授在Chem. Commun.上发表研究论文
Novel synthesis of N-alkyl amines from tandem coupling of either methylamine or nitroalkane with aldehyde

Shuanglong Lu,a   Jie Peng,a   Junjie Wu,a   Chao Li,a   Xueqin Caoa and   Hongwei Gu*a  

 

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, China 215123

 

Chem. Commun.,52, 760-763

 

A novel tandem strategy for coupling of either methylamine or nitroalkane with aldehyde has been developed. This is the first demonstration that methylamine or nitroalkane is used as a methylation reagent, fabricating N-alkyl amines. The active Pt NWs allow for the selective preparation of a series of N-alkyl amines with good to excellent yields under mild and environmentally friendly conditions.

                     

链接://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C5CC07807E#!divAbstract