a Laboratory of Advanced Optoelectronic Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, China
b Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China
J. Mater. Chem. A, 2016,4, 321-326
In this paper, we introduce a room-temperature mixed-solvent-vapor annealing (rtMSVA) method to fabricate high performance perovskite solar cells (pero-SCs) based on MAPbI3−xClx without the need for thermal annealing (TA). An ultra-smooth perovskite thin-film with high crystallinity was obtained by the DMF/CB mixed-solvent (1:20, v/v) vapor annealing at room-temperature without TA and the power conversion efficiency (PCE) of the pero-SCs reached 16.4%. More importantly, the reproducibility of the PCEs is quite good among 40 different devices. Furthermore, large active area pero-SCs were fabricated with the rtMSVA method. The PCEs of the pero-SCs based on ITO and flexible PET/Ag mesh electrodes with an active area of 1.21 cm2 reached 11.01% and 7.5%, respectively. We anticipate that rtMSVA would very possibly become a promising crystallization method for the fabrication of large area pero-SCs in the near future.
链接://pubs.rsc.org/en/content/articlelanding/2016/ta/c5ta08565a#!divAbstract