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Heterometallic transition metal clusters and cluster-supported coordination polymers derived from Tp- and Tp^*-based Mo(W) sulfido precursors

Wen-Hua Zhang^{a, b},   Quan Liu^{a, c}  and   Jian-Ping Lang^{a, b, *}(郎建平)  

^a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, People's Republic of China

^b Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, People's Republic of China

^c College of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, People's Republic of China

Coordination Chemistry Reviews 2015, 293–294, 187–210

This review summarizes the uses of Tp- and Tp^*-based Mo(W) sulfido precursor compounds, namely, [Et₄N][Tp^*WS₃] (P1), [Et₄N][Tp^*MoS(S₄)] (P2), [Et₄N][TpMoS(S₄)] (P3) and [(Tp^*WS₂)₂(μ-S₂)] (P4) for the assembly of a diverse class of heterometallic clusters, predominantly Mo(W)-Cu-S clusters. Some of these clusters also feature as building blocks for cluster-supported coordination polymers to achieve enhanced third-order nonlinear optical performances.

链接：

//www.sciencedirect.com/science/article/pii/S0010854514003439#