博彩平台

Zirconium catalysed intermolecular hydroamination reactions of secondary amines with alkynes

Qiu Sun^a,   Yaorong Wang^b,   Dan Yuan^*a(袁丹),   Yingming Yao^*a(姚英明)  and   Qi Shen^a

^a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Dushu Lake Campus, Soochow University, Suzhou 215123, People's Republic of China

Chem. Commun. 2015, 51, 7633-7636

An in situ generated cationic zirconium complex stabilized by an n-butylamine-bridged bis(phenolato) ligand has been developed to catalyse hydroamination reactions of secondary amines, which is the first example of group 4 metal based catalysts capable of mediating intermolecular hydroamination reactions of N-aryl/alkyl amines.

链接：

//pubs.rsc.org/en/content/articlelanding/2015/cc/c5cc01780g#!divAbstract