Shun-Jun Ji*(纪顺俊)
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215123, P. R. China
Org. Lett. 2015, 17, 1974–1977
An I2/CHP-mediated cross-coupling reaction of isocyanides with readily accessible amines via C–N formation is described for carbodiimide synthesis in moderate to excellent yields. This represents a metal-free strategy for a coupling reaction of isocyanides with amines, and it provides an efficient approach for symmetric and unsymmetric functionalized carbodiimide derivative synthesis under mild conditions.
链接：
//pubs.acs.org/doi/abs/10.1021/acs.orglett.5b00722
