Feng Yan*† (严锋)
†Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, and ‡Jiangsu Key Laboratory of Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials (FUNSOM) and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215123, P. R. China
Macromolecules 2014, 47, 6740–6747
The synthesis and characterization of pyrrolidinium cation based anion exchange membranes (AEMs) are reported. Pyrrolidinium cations with various N-substituents (including methyl, ethyl, butyl, octyl, isopropyl, 2-hydroxylethyl, benzyl, and cyclohexylmethyl groups) were synthesized and investigated with respect to their chemical stability in alkaline media. The influence of substitutions on alkaline stability of pyrrolidinium cations was investigated by quantitative 1H nuclear magnetic resonance spectroscopy (NMR) and theoretical approaches. N,N-Ethylmethyl-substituted pyrrolidinium cation ([EMPy]+) exhibited the highest alkaline stability in this study. The synthesized AEMs based on [EMPy]+ show promising alkaline stability in strongly basic solution. The study of this work should provide a feasible way for improving the alkaline stability of pyrrolidinium cation based AEMs.
链接：
//pubs.acs.org/doi/abs/10.1021/ma5015148?journalCode=mamobx
