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纪顺俊教授与汪顺义副教授合作在Chem. Commun.发表研究论文

Mn(III)-mediated reactions of 2-isocyanobiaryl with 1,3-dicarbonyl compounds: efficient synthesis of 6-alkylated and 6-monofluoro-alkylated phenanthridines

Jia-Jia Cao,   Xiang Wang,   Shun-Yi Wang*(汪顺义)  and   Shun-Jun Ji*  (纪顺俊)

 

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry,Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

Chem. Commun. 2014, 50, 12892-12895

 

Mn(III)-mediated reactions of 2-isocyanobiaryls with 1,3-dicarbonyl compounds were described for the construction of 6-alkylated and 6-monofluoro-alkylated phenanthridines in moderate to good yields. The reaction involves formation of two new C–C bonds and one C–C bond cleavage.

 

链接:

//pubs.rsc.org/en/Content/ArticleLanding/2014/CC/C4CC05324A