博彩平台

Interfacial hydrogenation and deamination of nitriles to selectively synthesize tertiary amines

Shuanglong Lu,^a   Chao Li^a  ,   Jiaqing Wang,^a   Yue Pan,^a   Xueqing Cao^a  and   Hongwei Gu*^a  (顾宏伟)

^a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, China

Chem. Commun. 2014, 50, 11110-11113

A novel one-pot method has been developed for the interfacial hydrogenation of nitriles to synthesize asymmetrical tertiary amines. The active Pt NWs allow for the preparation of a series of tertiary amines in excellent yields (up to 99.0%) and a mixed solvent is vital for the adjustment of the yield. And also, the reaction proceeded under mild conditions and is environmentally friendly.

链接：

//pubs.rsc.org/en/Content/ArticleLanding/2014/CC/C4CC05132G#!divAbstract