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纪顺俊教授与徐小平副教授合作在Chem. Commun.发表研究论文

Radical phosphinylation of a,a-diaryl allylic alcohols with concomitant 1,2-aryl migration

Xue-Qiang Chu,a   You Zia,   Hua Meng,a   Xiao-Ping Xu*a  (徐小平)  and   Shun-Jun Ji*a  (纪顺俊)

 

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, 215123, People's Republic of China

Chem. Commun. 2014, 50, 7642-7645

 

A novel radical phosphinylation of α,α-diaryl allylic alcohols with arylphosphine oxides was described for the direct preparation of α-aryl-β-phosphinylated carbonyl ketones in medium to good yields via 1,2-aryl migration. In this reaction, formation of new C(Ar)–C(sp3) and C(sp3)–P bonds was observed.

 

链接:

//pubs.rsc.org/en/Content/ArticleLanding/2014/CC/C4CC02114B#!divAbstract