,( 纪顺俊)
a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, 215123, People's Republic of China
Chem. Commun. 2014, 50, 7642-7645
A novel radical phosphinylation of α,α-diaryl allylic alcohols with arylphosphine oxides was described for the direct preparation of α-aryl-β-phosphinylated carbonyl ketones in medium to good yields via 1,2-aryl migration. In this reaction, formation of new C(Ar)–C(sp3) and C(sp3)–P bonds was observed.
链接:
//pubs.rsc.org/en/Content/ArticleLanding/2014/CC/C4CC02114B#!divAbstract