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Catalytic production of cyclic carbonates mediated by lanthanide phenolates under mild conditions

Jie Qin,^a   Peng Wang,^a   Qingyan Li,^a   Yong Zhang,^a   Dan Yuan^a   and   Yingming Yao*^ab  (姚英明)

^a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Dushu Lake Campus, Soochow University, Suzhou 215123, People's Republic of China

^b The Institute of Low Carbon Economy, Suzhou 215123, People's Republic of China

Chem. Commun. 2014, 50, 10952-10955

Readily available lanthanide complexes stabilized by a bridged poly(phenolate) ligand have been used for the first time as efficient catalysts for the insertion of CO2 into epoxides to generate cyclic carbonates with high activity, high selectivity, and a wide substrate scope under mild conditions.

链接：

//pubs.rsc.org/en/Content/ArticleLanding/2014/CC/C4CC02065K#!divAbstract