a Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, PR China
CrystEngComm 2014, 16, 6547-6551
A novel azobenzene (Azo) monomer was synthesized and employed to produce Azo-containing covalent organic frameworks (Azo-COF) through the borate ester formation reaction. The trans-to-cis photoisomerization of Azo units in Azo-COF occurred under irradiation with 365 nm UV light. The photoisomerization of Azo units could decrease the crystallinity of Azo-COF but could not change the pore size of Azo-COF.
链接：
//pubs.rsc.org/en/Content/ArticleLanding/2014/CE/C4CE00369A#!divAbstract
