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纪顺俊教授与汪顺义副教授合作在Chem. Commun.发表封面论文

tert-Butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane: efficient synthesis of 6-alkyl phenanthridines via C(sp3)–H/C(sp2)–H bond functionalization

Jia-Jia Cao,a   Tong-Hao Zhu,a   Shun-Yi Wang,*a (汪顺义)Zheng-Yang Gu,a   Xiang Wanga and   Shun-Jun Ji*a(纪顺俊)

 

a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

Chem. Commun. 2014, 50, 6439-6442.

 

An efficient method for the construction of 6-alkyl phenanthridines by tert-butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane was established. Two new C–C bonds were formed in this reaction via a sequential C(sp3)–H/C(sp2)–H bond functionalization under metal-free conditions.

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//pubs.rsc.org/en/content/articlelanding/2014/cc/c4cc00743c#!divAbstract