Co-Catalyzed Synthesis of 1,4-Dicarbonyl Compounds Using TBHP Oxidant
Feng Zhang , Peng Du , Jijun Chen , Hongxiang Wang , Qiang Luo , and Xiaobing Wan * (万小兵)
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
Org. Lett. 2014, 16, 1932–1935
A Co-catalyzed reaction for the construction of 1,4-dicarbonyls has been reported in which cascade organocobalt addition/trapping/Kornblum– DeLaMare rearrangement were involved. In view of the easy availability of starting materials, wide substrate scope, high functionality tolerance, and operational simplicity, this protocol constituted a simple, practical, and powerful alternative compared with previous approaches.
链接： //pubs.acs.org/doi/abs/10.1021/ol5004687
