Visible Light Mediated Fast Iterative RAFT Synthesis of Amino-Based Reactive Copolymers in Water at 20 °C
Jianyu Tong, Yi Shi, Guhuan Liu, Tao Huang, Na Xu, Zhengguang Zhu, Yuanli Cai*(蔡远利)
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, China
Macromol. Rapid Commun. 2013, 34, 1827–1832.
The attempts to mediate iterative RAFT polymerization of ionic monomers through visible light irradiation in water at 20 °C is reported, in which complete conversions are attained in several tens of minutes and the propagation suspends/restarts immediately for multiple times on cycling irradiation. This technique suits the one-pot synthesis of NH2/imidazole-based polymers with tuned structures from homo to random, block, random-block, and block-random-block, thus is robust and promising to control the sequence of the ionized water-soluble reactive copolymers.
链接：
//onlinelibrary.wiley.com/doi/10.1002/marc.201300697/abstract
