Bis-quaternary ammonium cation-based organic ionic plastic crystals: plastic crystal behaviour and ionic liquid properties above melting points
Chengzhen Shi,a Shichao Li,a Wei Zhang,a Lihua Qiua and Feng Yan*a (严锋)
a Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, China
J. Mater. Chem. A 2013, 1, 13956-13962.
A new family of organic ionic plastic crystals (OIPCs) based on bis-quaternary ammonium cations was synthesized and characterized. The synthesized bis-quaternary ammonium salts with bis(trifluoromethanesulfonyl) imide (TFSI−) anions exhibit plastic crystal properties as determined by differential scanning calorimetry (DSC). The high ionic conductivity of the compounds in the solid-state indicated that this new family of OIPCs can be promising solid-state electrolytes for electrochemical devices. Cyclic voltammetry characterization of OIPCs in the liquid-state revealed their wide electrochemical windows and highly reversible lithium metal electrodeposition properties.
链接： //pubs.rsc.org/en/content/articlelanding/2013/ta/c3ta12712e#!divAbstract
