Dual role of allylsamarium bromide as a Grignard reagent and a single electron transfer reagent in the one-pot synthesis of terminal olefins
Ying Li,a Yuan-Yuan Hua, Song-Lin Zhang*a （张松林）
a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China
Chem. Commun. 2013, 49, 10635-10637
The utility of allylsamarium bromide, both as a nucleophilic reagent and a single-electron transfer reagent, in the reaction of carbonyl compounds with allylsamarium bromide in the presence of diethyl phosphate is reported in this communication. From a synthetic point of view, a simple one-pot method for the preparation of terminal olefins is developed.
链接： //pubs.rsc.org/en/content/articlelanding/2013/cc/c3cc45611k#!divAbstract
