Xiaoqing Zeng1,*（曾小庆）, Helmut Beckers2,*, Helge Willner2
1College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 215123 Suzhou (China)
2FB C-Anorganische Chemie, Bergische Universität Wuppertal, Gaussstrasse 20, 42119 Wuppertal (Germany)
Angew. Chem. Int. Ed. 2013, 52, 7981–7984.
The novel iminyl radical O2SN, a SO3 analogue, was produced by flash vacuum pyrolysis of gaseous alkyl sulfonyl azides RSO2N3 (R=CF3, CH3) mixed with argon. Photoisomerization (λ>360 nm) of O2SN into planar syn-OSNO and anti-OSNO (see picture) was observed in solid noble-gas matrices.
链接： //onlinelibrary.wiley.com/doi/10.1002/anie.201302968/abstract
