博彩平台

博彩平台  科学研究  高水平论文
郎建平教授在Chem. Commun.发表研究论文

[Pb(Tab)2(4,4′-bipy)](PF6)2: two-step ambient temperature quantitative solid-state synthesis, structure and dielectric properties

Fan Wang,a   Chun-Yan Ni,a   Quan Liu,a   Fu-Ling Li,a   Jing Shi,a   Hong-Xi Lia and   Jian-Ping Lang*ab (郎建平) 

a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China

 

Chem. Commun. 2013, 49, 9248-9250.

 

Ambient temperature solid-state reaction of Pb(OAc)2 with TabHPF6 afforded an intermediate product [Pb(Tab)2]2(PF6)4, which further reacted with 4,4′-bipy in the solid state to generate a unique 2D cationic coordination polymer [Pb(Tab)2(4,4′-bipy)](PF6)2 in quantitative yield. Both complexes possess a low dielectric constant and low dielectric loss in the high electric field frequency range.

 



链接： //pubs.rsc.org/en/Content/ArticleLanding/2013/CC/c3cc45066j#!divAbstract