A Method for Synthesis of Homoallylic Bromide
Wenke Qi , Peipei Wang , Liyuan Fan , and Songlin Zhang * （张松林）
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Dushu Lake Campus, Soochow University, Suzhou 215123, People’s Republic of China
J. Org. Chem. 2013, 78, 5918–5924.
Cyclopropyl Grignard reagents react with carbonyl compounds in the presence of diethyl phosphite to give homoallylic bromides. The reaction is effectively carried out under mild conditions in a one-pot fashion with moderate to good yields.
链接： //pubs.acs.org/doi/abs/10.1021/jo400580n
