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胡传江教授与美国东北大学J. Timothy Sage教授、美国圣母大学W. Robert Scheidt教授合作在Inorg. Chem.发表研究论文

Effects of Imidazole Deprotonation on Vibrational Spectra of High-Spin Iron(II) Porphyrinates
 

Chuanjiang Hu *†‡（胡传江）, Qian Peng ‡, Nathan J. Silvernail ‡, Alexander Barabanschikov §, Jiyong Zhao , E. Ercan Alp , Wolfgang Sturhahn , J. Timothy Sage *§, and W. Robert Scheidt *‡

† Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P.R. China

‡ Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, United States

§ Department of Physics and Center for Interdisciplinary Research on Complex Systems, Northeastern University, Boston, Massachusetts 02115, United States

Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, United States


Inorg. Chem. 2013, 52, 3170–3177.
The effects of the deprotonation of coordinated imidazole on the dynamics of five-coordinate high-spin iron(II) porphyrinates have been investigated using nuclear resonance vibrational spectroscopy. Two complexes have been studied in detail with both powder and oriented single-crystal measurements. Changes in the vibrational spectra are clearly related to structural differences in the molecular structures that occur when imidazole is deprotonated.