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郎建平教授在Chem. Commun.发表研究论文

Stepwise ligand transformations through [2+2] photodimerization and hydrothermal in situ oxidation reactions

Dong Liu,ab   Jian-Ping Lang*a (郎建平)and   Brendan F. Abrahamsc  

 

a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 RenAi Road, Suzhou 215123, P. R. China

b College of Chemistry and Materials Science, Huaibei Normal University, Huaibei 235000, P. R. China

c School of Chemistry, University of Melbourne, Australia

 

Chem. Commun. 2013, 49, 2682-2684. 

The SCSC transformation of a 1D polymer [Cd(1,3-bdc)(4-spy)2]n produced a 2D polymer [Cd(1,3-bdc)(4-spy)(HT-ppcb)0.5]n through the [2+2] photodimerization reaction. Hydrothermal reactions of HT-ppcb with CdCl2, 1,3-H2bdc and H2O2 afforded another 2D polymer {[Cd(H2O)(1,3-bdc)(bpbpf)]·H2O}n in which HT-ppcb underwent in situ oxidation to form a unique furan-based ligand bpbpf.



链接://pubs.rsc.org/en/content/articlelanding/2013/cc/c3cc39286d#!divAbstract