Enhanced water stability of MOFs via multiple hydrogen bonds and their application in water harvesting
Yi-Chao Wang1, Mo-Han Chen1, Zi-Wen Fan1, Yue Wang,1 Cai-Xiang Huang1, Hui-Fang Wang1（王会芳）*, Jian-Ping Lang1,2（郎建平）*, Zheng Niu1（牛政）*
1College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.
2State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Chem. Commun. 2024, 60, 10692-10695
Abstract: A mechanism based on multiple hydrogen bonds was proposed to describe the great water stability of some hydrated Cu paddle-wheel-based MOFs, which was demonstrated through density functional theory (DFT) calculations and single-crystal X-ray diffraction (SCXRD) of water-loaded MOFs. This mechanism endowed Cu-TDPAT with exceptional water stability and outstanding atmospheric water harvesting capability.
链接：//pubs.rsc.org/en/content/articlelanding/2024/cc/d4cc03654a
