博彩平台

Tel: 86-512-65880341 (Lab)

Fax: 86-512-65880305 (O.)

学历及学术经历：

1992年苏州大学化学教育专业本科毕业，1995年苏州大学有机化学专业毕业，获硕士学位，期间赴南开大学做访问学者1年。1995年留校工作至今，2006年获有机化学博士学位。

主持国家自然科学基金2项，江苏省高等学校自然科学研究重大项目1项，江苏省高校自然科学研究项目1项，参加3项国家自然科学基金项目和1项省部级项目。在国内外化学核心期刊如Green Chem., Org. Lett., Org. Chem. Front., J. Org. Chem., Dalton Trans., Organometallics, Catal. Sci. Technol., J. Polym. Sci. Polym. Chem.等发表论文40余篇，授权中国发明专利19项。曾获江苏省科学技术进步奖二等奖1项，获得中国石油和化学工业协会科学技术进步奖一等奖1项。2011-2012年获得江苏政府留学基金资助出国访学1年。

主要教学成果：

主持国家级一流本科课程1门，省级一流本科课程1门；主持完成江苏省教育厅教材建设项目1项，苏州大学3I工程《有机化学》和《有机化学实验》微课程建设，有机化学校课程思政团队建设、基础化学实验教学团队建设等校级项目7项；主编“十三五”江苏省高等学校重点教材《有机化学》（上、下）一套（高教出版社）；副主编《有机化学实验》（高教出版社）、《有机化学实验》（南京大学出版社）；参编《有机化学》（高教出版社）、《有机化学演示实验（音像）》（高教出版社）和《有机硫化学》等教材6部；在《大学化学》、《实验室科学》等期刊发表教学论文10余篇；获得江苏省教学成果一等奖，江苏省高校第三届多媒体课件制作大赛三等奖，江苏省高校微课教学本科组三等奖，江苏省优秀毕业设计团队奖和苏州大学利苏奖教金、交行教学奖和周氏教学优胜奖等奖励10多项。

研究领域：稀土金属有机化合物的合成、结构及其在不对称催化反应中的应用，二氧化碳化学转化等。

Representative Publications:

1. Deoxygenative hydroboration of aromatic nitro compounds catalyzed by tetra(diisopropylamido) rare-earth metal-lithium bimetallic complexes

C. L. Chen, C. R. Lu*, B. Zhao*

J. Org. Chem. 2023, doi.org/10.1021/acs.joc.3c01905

2.Enantioselective Michael addition of malononitrile to unsaturated ketones catalyzed by rare-earth metal amides RE[N(SiMe₃)₂]₃ with phenoxy-functionalized TsDPEN ligands

Y. Y. Ren, Q. S. Yu, C. R. Lu*, B. Zhao*

J. Org. Chem. 2023, 88, 13205–13213

3. Asymmetric hydrophosphonylation of α,β-unsaturated ketones catalyzed by rare-earth metal complexes bearing Trost ligands

H. F. Song, Y. L. Sun, C. R. Lu*, B. Zhao*

J. Org. Chem. 2022, 87, 7747-7762

4. Enantioselective Hydroboration of Ketones Catalyzed by Rare-Earth- Metal Complexes Supported with Phenoxy-Functionalized TsDPEN Ligands

Q. S. Yu, C. R. Lu*, B. Zhao*

Organometallics,2021, 40, 2529-2537

5. Nickel(0)-induced β‑H elimination of magnesium alkyls: formation and reactivity of heterometallic hydrides

J. S. Huang, X. Z. Zheng, I. D. Rosal, B. Zhao*, L. Maron*, X. Xu*

Inorg. Chem.2020, 59, 13473-13480

6. Enantioselective Hydroboration of Ketones Catalyzed by Rare-Earth Metal Complexes Containing Trost Ligands

Y. L. Sun, C. R. Lu*, B. Zhao*, M. Q. Xue

J. Org. Chem. 2020, 85, 10504-10513

7. Cycloaddition of Aziridine with CO2/CS2 Catalyzed by Amidato Divalent Lanthanide Complexes

Y. Q. Xie, C. R. Lu*, B. Zhao*, Q. Y. Wang, Y. M. Yao

J. Org. Chem. 2019, 84, 1951-1958

8. Intermolecular addition of alcohols to carbodiimides catalyzed by rare-earth metal amides

L. J. Hu, C. R. Lu, B. Zhao*, Y. M. Yao

Org. Chem. Front., 2018, 5, 905-908

9. An amidato divalent ytterbium cluster: synthesis and molecular structure, its reactivity to carbodiimides and application in the guanylation reaction

C. Gong, H. Ding, C. R. Lu, B. Zhao*, Y. M. Yao

Dalton Trans., 2017, 46, 6031-6038.

10. Synthesis and characterization of bridged bis(amidato) rare earth metal amides and their applications in C–N bond formation reactions

B. Zhao,* Y. Xiao, D. Yuan, C. R. Lu, Y. M. Yao

Dalton Trans.2016, 45, 3880-3887.

11. Synthesis and characterization of amidato divalent lanthanide complexes and their use in forming 2,4-quinazolidinones from CO₂ and 2-aminobenzonitriles

Q. Y. Wang,C. R. Lu,B. Zhao*, Y. M. Yao

Eur. J. Org. Chem., 2016, 2555-2559.

12. Carboxylation of terminal alkynes with CO₂ catalyzed by bis(amidate) rare-earth metal amides

H. Cheng, B. Zhao,* Y. M. Yao, C. R. Lu

Green Chem.,2015, 17, 1675-1682.

13. Highly enantioselective epoxidation of α,β-unsaturated ketones catalyzed by rare-earth amides [(Me₃Si)₂N]₃RE(μ-Cl)Li(THF)₃ with phenoxy-functionalized chiral prolinols

C. Zeng, D. Yuan, B. Zhao,* Y. M. Yao

Org. Lett., 2015, 17, 2242-2245.

14. Asymmetric epoxidation of unsaturated ketones catalyzed by heterobimetallic rare-earth-lithium complexes bearing phenoxy functionalized chiral diphenylprolinolate ligand

Q. Q. Qian, Y. F. Tan, B. Zhao,* T. Feng, Q. Shen, Y. M. Yao*

Org. Lett., 2014, 16, 4516-4519.

15. Asymmetric hetero-Diels-Alder reaction of Danishefsky’s dienes with a-carbonyl esters catalyzed by an indium(III)-PyBox complex

B. Zhao, T. P. Loh

Org. Lett., 2013, 15, 2914-2917.

16. Addition of terminal alkynes to aromatic nitriles catalyzed by divalent lnathanide amides supported by amidates: synthesis of ynones

H. Ding, C. R. Lu, X. L. Hu, B. Zhao*, B. Wu, Y. M. Yao*

Synlett, 2013, 24, 1269-1274.