朱健
教授,博士,博士生导师,学部副主任 高分子材料与工程专业负责人 苏州大学博彩平台 |
学历及学术经历:
分别于1995,1998和2004年在苏州大学获学士、硕士和博士学位。1998年留校任教。2006-2007和2009-2010在新加坡国立大学和宾夕法尼亚州立大学从事博士后工作。主持国家“十三五”重大专项子课题两项,国家自然科学基金项目四项,江苏省自然科学基金和教育厅重点项目各一项。积极与企业合作,共同开发各类产品,累计到账横向课题经费超千万元。获中国化工学会基础研究一等奖(2022年,第三),苏州大学教学成果一等奖(2022,第一),苏州大学苏鑫科研奖(2008,独立),江苏省科技进步二等奖(2009,第三)和教育部科技进步二等奖(2009,第三)。先后发表研究论文180多篇,获美国发明专利授权3项,澳大利亚发明专利授权2项,中国发明专利授权21项。
研究兴趣:
高分子精密合成;
含硒聚合物的设计与合成;
功能性高分子材料的结构设计与合成;
材料表面聚合物改性;
光引发聚合及其在3D打印中的应用研究;
刺激响应聚合物的制备和性能研究等。
荣誉
指导本科生参加第四届全国化学实验创新设计大赛,获全国一等奖,2023;
指导硕士生获江苏省优秀硕士学位论文,2023;
中国化工学会基础研究一等奖,排三,2022;
苏州大学教学成果一等奖,排一,2022;
指导国家级大学生创新实验计划(2013, 2016和2018)三项,结题优秀;
江苏省科技进步二等奖,排七,2013;
教育部自然科学奖二等奖,排七,2013;
教育部科技进步二等奖,排三,2010;
苏州市科技进步一等奖,排三,2009;
苏鑫科研奖,2008年。
近年来主持的部分项目:
1. 工信部2023年基础再造和制造业高质量发展专项项目,180万元,2024-2026;
2. 3D 打印动态交联-解交联活性聚合物材料的研究(SYG202350),苏州市第十八批科技计划(前言技术研究)项目,50万元,2024.7-2026.6;
3. 基于光引发RAFT逐步聚合构建聚合物可控降解策略(22371199),国家自然科学基金面上项目,50万元,2024.1-2027.12;
4. 聚乳酸工程塑料创制(2022YFB3704905),科技部重点研发计划项目子课题,80万元,2022-2025;
5. 企业委托项目,55万元,2021-2022;
6. 企业委托项目,30万元,2021-2022;
7. 企业委托项目,100万元,2021-2024;
8. 基于硒醚取代环状内酯的多功能集成聚酯合成(21871200),国家自然科学基金面上项目,65万元,2019.1-2022.12;
9. 企业委托项目,100万元,2019-2022;
10. 企业委托项目,100万元,2018-2021
11. 企业委托项目,100万元,2017-2020;
12. 企业委托项目,100万元,2017-2020;
13. 硒醚聚合物精密合成及其功能性研究(17KJA150008),江苏省高等学校自然科学研究重大项目,15万元,2017.9-2020.8.
14. 制笔新型环保材料(2016YFB0302600),科技部国家重点研发计划项目子课题,65万元,2016-2020
15. 拓扑结构热塑性弹性体的可控合成(BY2016051-01),江苏省科技计划项目-前瞻性联合研究项目,30万元,2016-2018
16. 企业委托项目,85万元,2015-2016
17. 企业委托项目,100万元,2016-2019
18. 基于有机硒化合物的通用型活性自由基聚合调控体系研究(21374067),国家自然科学基金,83万元,2013-2016
19. 偶氮苯光敏生物智能材料的活性自由基聚合法合成及其性能研究(50803044)2009-2011 国家自然科学基金,21万元
1. Xiaofeng Pan; Jiajia Li*; Zhuang Li; Qing Li; Xiangqiang Pan; Zhengbiao Zhang; Jian Zhu*, Tuning the Mechanical Properties of 3D-printed Objects by the RAFT Process: From Chain-Growth to Step-Growth, Angewandte Chemie International Edition, 2024, 63, e202318564
2. Bowen Zhao, Jiajia Li*, Xinrui Yang, Shiliang He, Xiangqiang Pan, Jian Zhu*, Degradable 3D Printed Objects with Tunable Mechanical Properties via Photoinduced Free Radical Promoted Cationic RAFT Polymerization, ACS Applied Polymer Materials, 2024, 6,2, 1584–1591
3. Xia Lin, Qianxi Gu, Jiajia Li*, Jian Zhu*, Zinc-Mediated Living Cationic Polymerization, ACS Macro Letters,2023, 12, 1692-1697
4. Sisi Chen, Vincent Scholiers, Mengyao Zhang, Jiandong Zhang, Jian Zhu,* Filip E. DuPrez,* and Xiangqiang Pan* , Thermally Responsive Selenide-containing Materials Based on Trans alkylation of Selenonium Salts, Angewandte Chemie International Edition, 2023, 62, e202309652
5. Xia Lin, Jiajia Li,* Wenjing Shu, Xiangqiang Pan and Jian Zhu*, Polyselenonium Salt as Heterogeneous Catalyst for Living/Controlled Cationic Polymerization, ACS Applied Polymer Materials, 2023, 5, 10, 8704-8711
6. Sisi Chen, Mengyao Zhang, Qingyuan Li, Jiachen Li, Shengpeng Wu, Jian Zhou, Guoqing Jin, Zhengbiao Zhang, Xiangqiang Pan*, and Jian Zhu*, Visible Light-Responsive Covalent Adaptable Liquid Crystal Elastomers Enabled by Dynamic Allyl Selenide Bonds, Macromolecules, 2023, 56, 15, 5765-5773
7. Wen-Jing Li, Xiang-Qiang Pan*, Jian Zhu*, and Zheng-Biao Zhang, Synthesis of Sulfur/Selenium-containing Polyester with Recyclability and Controllable Hydrophilicity and Glass Transition Temperature, Chinese Journal of Polymer Science, 2023, DOI:10.1007/s10118-023-2994-3
8. Miao Chen, Jiajia Li,* Dong Xing, Xiangqiang Pan, and Jian Zhu*, Tuning the Polymer Molecular Weight Distribution in Cationic RAFT Polymerization by Mixing Chain Transfer Agents, Chinese Journal of Chemistry, 2023, 41, 1684-1690
9. Bowen Zhao, Jiajia Li,* Guangliang Li, Xinrui Yang, Shaopu Lu, Xiangqiang Pan and Jian Zhu*, Fast Living 3D Printing via Free Radical Promoted Cationic RAFT Polymerization, Small, 2023, 2207637
10. Yingying Li, Xiaoliang Ma, Jiandong Zhang, Xiangqiang Pan, Na Li, Gaojian Chen*, Jian Zhu*, Degradable selenium-containing polymers for low cytotoxic antibacterial materials, ACS Macro Letters,2022, 11, 1349-1354
11. Zhuang Li, Jiajia Li*, Bowen Zhao, Xiaofeng Pan, Xiangqiang Pan, Jian Zhu*, Photoinduced RAFT Step-Growth Polymerization toward Degradable Living Polymer Networks, Chinese Journal of Chemistry, 2023, 41, 503-508
12. Bowen Zhao, Jiajia Li*, Zhuang Li, Xia Lin, Xiangqiang Pan, Zhengbiao Zhang, and Jian Zhu*, Photoinduced 3D Printing through a Combination of Cationic and Radical RAFT Polymerization, Macromolecules, 2022, 55, 16, 7181-7192
13. Xia Lin, Jiajia Li*, Na Li, Xiangqiang Pan, Zhengbiao Zhang, Jian Zhu*, Postpolymerization Modification and Topological Structure Design of Poly(vinyl ether)s Based on the Selective Addition Reaction of Electrophilic Selenium Reagent and Divinyl Monomers, ACS Applied Polymer Materials, 2022, 4, 8, 6229 - 6238
14. Bin Xu, Xiaoliang Ma, Anqi Dai, Xiaofeng Pan, Xiangqiang Pan, Na Li,* and Jian Zhu*, Fabrication of Multi-responsive Photonic Crystals based on Selenium-containing Copolymers, Polymer Chemistry, 2022, 13, 4290 - 4297
15. Dong Xing, Jiajia Li*, Miao Chen, Na Li, Xiangqiang Pan, Zhengbiao Zhang and Jian Zhu*, Controlling Polymer Molecular Weight Distributions by Light through RAFT-HDA Click Conjugation, Journal of Polymer Science, 2022
16. Xia Lin, Jiajia Li*, Xiangqiang Pan, Zhengbiao Zhang, and Jian Zhu*, Controlled Cationic Polymerization Using RAFT Agents with Selenonium Cations as Metal-Free Lewis Acids: From Homogeneous to Heterogeneous Catalysis, Polymer Chemistry, 2022, 13, 2757 - 2763
17. Bin Xu, Xiangqiang Pan*, Jian Zhu*, Fabrication of Oxidative and pH Dual-Responsive Photonic Crystals Based on Sulfide-Containing Block Copolymers, ACS Applied Polymer Materials, 2022, 4, 3315 - 3323
18. Bowen Zhao, Jiajia Li*, Yuan Xiu, Xiangqiang Pan, Zhengbiao Zhang, and Jian Zhu*, Xanthate-based Photoiniferter RAFT Polymerization toward Oxygen-tolerant and Rapid Living 3D Printing, Macromolecules, 2022, 55, 1620-1628
19. Sisi Chen, Weihong Lu, Jiandong Zhang, Hanliang He, Yujie Cang, Xiangqiang Pan*; Jian Zhu*, Thermally Driven Diselenide Metathesis: Polarization Process vs Radical Process, ACS Macro Letters,2022, 11, 264-269
20. Jiajia Li, Miao Chen, Xia Lin, Xiangqiang Pan, Zhengbiao Zhang, Jian Zhu*, Controlled Microflow Cationic Polymerization of Vinyl Ethers under Ambient Conditions, Chemical Engineering Journal, 2022, 435, 134828.
21. Zhuang Li, Jiajia Li*, Xiangqiang Pan, Zhengbiao Zhang, Jian Zhu*, Catalyst-Free, Visible-Light-Induced Step-Growth Polymerization by a Photo-RAFT Single-Unit Monomer Insertion Reaction, ACS Macro Letters,2022, 11, 230-235
22. Yingying Li, Dong Xing, Xiangqiang Pan, Jian Zhu*, Synthesis and Antibacterial Activity of Selenium-functionalized Poly(ε-caprolactone), Chinese Journal of Polymer Science, 2022, 40 (1), 67-74. doi:10.1007/s10118-021-2638-4
23. Bin Xu#, Shaoxiang Liu#, Yingying Li, Jiandong Zhang, Xiangqiang Pan*, and Jian Zhu*, Synthesis of precisely structured lefin copolymers by phenylseleno oxidation elimination, Macromolecular Chemistry and Physics, 2021, 2100351
24. Bowen Zhao, Jiajia Li*, Xiangqiang Pan, Zhengbiao Zhang, Guoqing Jin*, and Jian Zhu*, Photoinduced Free Radical Promoted Cationic RAFT Polymerization toward “Living” 3D Printing, ACS Macro Letters,2021, 10, 1315-1320
25. Qilong Li, Na Li*, Xiangqiang Pan, Jian Zhu*, Photo Masking via Breaking Alkyl C-Se Bond of Selenium Containing Maleimide Polymers by Ultraviolet Light, European Polymer Journal, 2021, 159, 110764
26. Shaoxiang Liu, Xiangqiang Pan, Jian Zhu*, A Facile Strategy to Construct versatile Fluorescent Probes for the Detection of Au3+ and Nitroaromatic, Reactive and Functional Polymers, 2021, 167, 105017.
27. Miao Chen, Jiajia Li*, Kaiqi Ma, Guoqin Jin, Xiangqiang Pan, Zhengbiao Zhang, Jian Zhu*, Controlling Polymer Molecular Weight Distribution through a Latent Mediator Strategy with Temporal Programming, Angewandte Chemie International Edition, 2021, 60, 19705-19709
28. Mengmeng Zhang, Jiajia Li*, Miao Chen, Xiangqiang Pan, Zhengbiao Zhang, Jian Zhu*, Combination of the Photoinduced Atom Transfer Radical Addition Reaction and Living Cationic Polymerization: A Latent Initiator Strategy toward Tailoring Polymer Molecular Weight Distributions, Macromolecules, 2021, 54, 6502-6510
29. Yuanyuan Zhang, Xiangqiang Pan*, and Jian Zhu*, Synthesis of Slenium-Containing Polystyrene Microspheres and Using as Catalyst for Oxidation of Acrolein, Polymers, 2021, 13, 1632
30. Jiajia Li, Andrew Kerr, Qiao Song, Jie Yang, Satu Häkkinen, Xiangqiang Pan, Zhengbiao Zhang, Jian Zhu,* and Sébastien Perrier*, Manganese Catalyzed Batch and Continuous Flow Cationic RAFT Polymerization Induced by Visible Light, ACS Macro Letters, 2021, 10, 570-575
31. Sisi Chen, Min Liu, Zhengbiao Zhang, Jian Zhu*, Xiangqiang Pan*, and Xiulin Zhu, Photoresponsive Dynamic Covalent Bond Based on Addition-Fragmentation Chain Transfer on Allyl Selenides, Polymer Chemistry, 2021, 12, 1622-1626
32. Shaoxiang Liu, Qilong Li, Yingying Li, Jiandong Zhang, Xiangqiang Pan*, Jian Zhu*, and Xiulin Zhu, Controllable Radical Polymerization of Selenide Functionalized Vinyl Monomers and Its Application in Redox Responsive Photonic Crystals, Macromolecular Rapid Communications, 2021, 2000764
33. Xia Lin, Jiajia Li*, Jiandong Zhang, Shaoxiang Liu, Xiangqiang Pan, Jian Zhu*, and Xiulin Zhu, Living cationic polymerization of vinyl ethers initiated by electrophilic selenium reagents under ambient conditions, Polymer Chemistry, 2021, 12 (7), 983-990
34. Jiajia Li, Miao Chen, Xia Lin, Qilong Li, Wei Zhang, Guoqing Jin, Xiangqiang Pan,* Jian Zhu,* and Xiulin Zhu, Near-Infrared, Light-Induced Cationic and Radical RAFT Polymerization Catalyzed by Iron Complex, ACS MacroLetters, 2020, 9, 1799-1805
35. Qilong Li, Shaoxiang Liu, Jiajia Li, Xiangqiang Pan*, Jian Zhu* and Xiulin Zhu, Visual Ozone Sensor: Structural Color Change of Pendant Selenium-Containing Maleimide Polymers via Oxidation, Macromolecular Rapid Communication, 2021, 42, 2000517.
36. Qilong Li, Yuanyuan Zhang, Zijun Chen, Xiangqiang Pan*, Zhengbiao Zhang*, Jian Zhu* and Xiulin Zhu, Organoselenium chemistry-based polymer Synthesis, Organic Chemistry Frontiers, 2020, 7, 2815-2841
37. Jiajia Li, Andrew Kerr, Satu Hakkinen, Thomas Floyd, Mengmeng Zhang, Xiangqiang Pan, Xiulin Zhu, Sebastien Perrier*, and Jian Zhu*, Manganese carbonyl induced cationic reversible addition-fragmentation chain transfer (C-RAFT) polymerization under visible light, Polymer Chemistry, 2020, 11, 2724-2731.
38. Jie Zhao, Xiangqiang Pan*, Jian Zhu*, and Xiulin Zhu, Novel AIEgen-Functionalized Diselenide-Crosslinker Polymer Gels as Fluorescent Probes and Drug Release Carriers, Polymers, 2020, 12(3), 551.
39. Ya’nan Wang, Xiaofang Lin, Zhengbiao Zhang, Jian Zhu,* Xiangqiang Pan,* and Xiulin Zhu, A novel synthesis of poly(ester‐alt‐selenide)s by ring‐opening copolymerization of γ‐ selenobutyrolactone and epoxy monomer, Polymers2020, 12, 1203.
40. Sisi Chen, Xiangqiang Pan*, Jian Zhu*, and Xiulin Zhu, Synthesis of selenide-containing polymers by multicomponent polymerization based on γ-butyroselenolactone, Polymer Chemistry, 2019, 10, 6395-6400
41. Qilong Li, Shaoxiang Liu, Mingfeng Xu, Na Li*, Xiangqiang Pan, Jian Zhu*, and Xiulin Zhu, Selenide-Containing Soluble Polyimides: High Refractive Index and Redox Responsiveness, Eur. Polym. J., 2020, 122, 109358
42. Jiajia Li, Mengmeng Zhang, Jian Zhu*, and Xiulin Zhu, Investigation into the Direct Photolysis Process of Photo-Induced RAFT Polymerization by ESR Spin Trapping, Polymers, 2019, 11, 1722.
43. Qilong Li, Kar Lok Ng, Xiangqiang Pan*, and Jian Zhu*, Synthesis of high refractive index polymer with pendent selenium-containing maleimide and use as a redox sensor, Polymer Chemistry, 2019, 10, 4279-4286
44. Jin’an Wu, Chunlai Ding, Dong Xin, Zhengbiao Zhang, Xiaofei Huang, Xiulin Zhu, Xiangqiang Pan* and Jian Zhu*, Functionalization of Poly(e-caprolactone) as a Versatile Platform Using e-(a-Phenylseleno) Caprolactone as a Monomer, Polymer Chemistry, 2019, 10, 3851-3858
45. Zhuangfei Qian, Yuanyuan Zhang, Xiangqiang Pan, Na Li*, Jian Zhu*, and Xiulin Zhu, Selenium-doped phenolic resin spheres: Ultra-high adsorption capacity of noble metals, Reactive and Functional Polymers, 2019, 142, 223-230
46. Jiajia Li, Mengmeng Zhang, Xiangqiang Pan*, Zhengbiao Zhang*, Sebastien Perrier, Jian Zhu* and Xiulin Zhu, Visible Light Induced Controlled Cationic Polymerization by in situ Generated Catalyst from Manganese Carbonyl, Chemical Communications, 2019, 55, 7045-7048. DOI: 10.1039/c9cc03317c
47. Yuqing Qian, Xiaowei An, Xiaofei Huang, Xiangqiang Pan*, Jian Zhu*, and Xiulin Zhu, Recyclable Self-Healing Polyurethane Cross-linked by Alkyl Diselenide with Enhanced Mechanical Properties, Polymers, 2019, 11, 773.
48. Xiaowei An, Weihong Lu, Jian Zhu*, Xiangqiang Pan*, and Xiulin Zhu, Selenol-Based Nucleophilic Reaction for the Preparation of Reactive Oxygen Species-Responsive Amphiphilic Diblock Copolymers, Polymers, 2019, 11, 827.
49. Ping Xu, Xiaofei Huang, Xiangqiang Pan, Na Li*, Jian Zhu*, and Xiulin Zhu, Hyperbranched Polycaprolactone through RAFT Polymerization of 2-Methylene-1,3-dioxepane, Polymers, 2019, 11, 318.
50. Xiaowei An, Weihong Lu, Minglun Pang, Zhengbiao Zhang, Xiulin Zhu, Jian Zhu*, and Xiangqiang Pan*, One-pot cascade polymerization based on the addition reactions of electrophilic selenium reagents to alkenes, Polymer Chemistry, 2019, 10, 574-581.